2025Muenks EmeraldID

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Citation

Muenks, A., Farrell, D.P., Zhou, G. and DiMaio, F. 2025. Automated identification of small molecules in cryoelectron microscopy data with density-and energy-guided evaluation. Structure. 33, 10 (2025), 1760–1770.

Abstract

Methodological improvements in cryoelectron microscopy (cryo-EM) have made it useful in ligandbound structure determination for biology and drug design. However, determining ligand conformation and identity is challenging at the resolutions typical for cryo-EM. Automated methods can aid in ligand conformational modeling, but current ligand identification tools—developed for X-ray crystallography data—perform poorly at resolutions common for cryo-EM. Here, we present EMERALD-ID, a method capable of docking and evaluating small molecule conformations for ligand identification. EMERALDID identifies 44% of common ligands exactly and identifies closely related ligands in 66% of cases. We then use this tool to discover possible ligand identification errors, as well as previously unidentified ligands. Furthermore, we show EMERALD-ID identifying ligands from custom ligand libraries of various small molecule types, including human metabolites and drug fragments. Our method provides a valuable addition to cryo-EM modeling tools to improve small molecule model accuracy and quality.

Keywords

https://www.cell.com/structure/fulltext/S0969-2126(25)00250-3

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